Cardinal Luis María de Borbón y Vallabriga (1777-1823) was the Countess of Chinchón’s brother and the son of the Infante Luis de Borbón and María Teresa de Vallabriga, whose morganatic marriage obliged them to live away from the court (María Teresa was from the minor nobility). It was only after Luis María’s appointment as archbishop of Seville in 1799 that Charles IV allowed him to use his father’s surname. In 1800 he became cardinal and archbishop of Toledo. Here he wears the emblems of the order of Charles III and the Neapolitan ones of Saint Ferdinand of Merit and of Saint Januarius, granted to him in 1793, 1800 and 1802 respectively.